Synthesis of the dioxygen complex of oil cobalt (II) porphyrin complex and study of its oxygenating properties
No. 28 (2019), CONTENTS
No. 28 (2019)

Synthesis of the dioxygen complex of oil cobalt (II) porphyrin complex and study of its oxygenating properties

CONTENTS
https://doi.org/10.15407/kataliz2019.28.069
Published November 20, 2019
M.M. Aghaguseynova
Azerbaijan State Oil and Industry University
G.I. Amanullayeva
Azerbaijan State Oil and Industry University
Z.E. Bayramova
Azerbaijan State Oil and Industry University
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Aghaguseynova, M., Amanullayeva, G., & Bayramova, Z. (2019). Synthesis of the dioxygen complex of oil cobalt (II) porphyrin complex and study of its oxygenating properties . Catalysis and Petrochemistry, (28), 69-72. https://doi.org/10.15407/kataliz2019.28.069
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Abstract

Based on the porphyrin concentrate extracted from oil, a cobalt (II) porphyrin complex and its dioxygen adduct have been synthesized. The structure of resulting complexes has been established by studying their electronic and IR spectra. The molecular weight of the oil cobalt (II) porphyrin complex, determined by the mass spectroscopic method, was 456. The molar ratio of cobalt (II) porphyrin complex and molecular oxygen is 2 : 1. It has been established that the dioxygen adduct of cobalt (II) porphyrin complex possesses the ability to epoxidize alkenes. A possible mechanism for epoxidation of alkenes has been considered.

https://doi.org/10.15407/kataliz2019.28.069
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