Ключові слова
Як цитувати
Анотація
В хронологічному порядку описано результати досліджень відділу гетерогенного кислотно-основного каталізу ІСПЕ НАНУ в 2003-2023 роках. Вони стосуються синтезу, вивчення та застосування твердих суперкислот (H0 < -12) WO3/ZrO2, WO3/ZrO2-SiO2, ZrO2SiO2-Al2O3, ZrO2SiO2-SnO2, як каталізаторів, зокрема в крекінгу вакуумного газойлю, реакціях алкілування ізобутану ізобутанолом, ацилування толуолу, олігомеризації тетрогідрофурану, ацилювання метил-третбутилового етеру. Роботи фундаментального характеру стосуються встановлення кореляцій між силою кислотних центрів каталізатора і його активності, зокрема, в реакції дегідратації С2-С4 спиртів, та пошуку кореляцій між здатністю первинних і вторинних спиртів до дегідрування та окиснення і їх хімічними зсувами δ (R17OH) та δ (R13СОH). Вперше було виміряно значення функції кислотності Гаммета за підвищених (до 200 °С) температур для ряду твердих кислот. Зокрема для H-Y фожазиту, H0 досягає суперкислотних значень при 160 °С.
З 2010 року основна увага приділяється каталітичній конверсії відновлювальної сировини, переважно біоспиртів (етанол, гліцерин) та С6 вуглеводів, в такі продукти органічного синтезу, як етилацетат, 1,1 діетоксиетан, н-бутанол, пропіленгліколь, алкіл лактати, лактид, гліколід. Спільно з ТОВ «Виробнича група Техінсервіс» розроблено нові процеси одержання етилацетату, 1,1 діетоксиетану, н-бутанолу з біоетанолу та рацемічного лактиду з гліцерину, а також розроблено нові технології одержання пропілен оксиду з пропілену та пероксиду водню (НРРОа-процес); паро фазного гідрування піролізної С4-5 фракції; прямого високо-температурного хлорування етилену до вініл хлориду для Калуського «Карпатнафтохім». НРРОа установку (2000 т/рік) було запущено на «Карпатнафтохімі» в 2020 році.
Посилання
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