Catalytic Oxidation of Aromatic Aldehydes on Se-Modified Microgels
No. 35 (2024), CONTENTS
No. 35 (2024)

Catalytic Oxidation of Aromatic Aldehydes on Se-Modified Microgels

CONTENTS
https://doi.org/10.15407/kataliz2024.35.032
Published December 10, 2024
Anastasiia S. Pavliuk
Lviv Polytechnic National University 12 S. Bandera Str., Lviv, 79013, Ukraine
Volodymyr V. Ivasiv
Lviv Polytechnic National University 12 S. Bandera Str., Lviv, 79013, Ukraine
Roman V. Nebesnyi
Lviv Polytechnic National University 12 S. Bandera Str., Lviv, 79013, Ukraine
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Keywords

catalysis, oxidation processes, heterogeneous systems, aromatic aldehydes, microgel catalysts

How to Cite

Pavliuk, A. S., Ivasiv, V. V., & Nebesnyi, R. V. (2024). Catalytic Oxidation of Aromatic Aldehydes on Se-Modified Microgels. Catalysis and Petrochemistry, (35), 32-40. https://doi.org/10.15407/kataliz2024.35.032
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Abstract

The aim of this work is to investigate the catalytic activity of Se-modified microgels in the heterogeneous oxidation of aromatic aldehydes. The study tested heterogeneous systems with organic solvent-to-water volume ratios of 1 : 4, 1 : 1, and 4 : 1. The dependence of benzoic acid yield on reaction temperature was examined across a range from 20 °C to 60 °C. It was established that the synthesized selenium-modified microgel catalysts with a 3D polymer structure enable a benzoic acid yield of 87.0 % (with selectivity of 89.4 %) in the heterogeneous oxidation of benzaldehyde with hydrogen peroxide, at a benzene-to-water ratio of 1 : 1 and a reaction temperature of 50 °C. The catalytic oxidation processes of several aromatic aldehydes – benzaldehyde, cinnamaldehyde, anisaldehyde, and veratraldehyde – were studied in a biphasic organic solvent/water system. The oxidation of aromatic aldehydes resulted in valuable products for the pharmaceutical and cosmetic industries, including aromatic acids, mequinol, hydrocoumarin, and 3,4-dimethoxyphenol. The synthesized Se-containing microgel catalysts enable mild process conditions, high yields, and high selectivity, which enhance process efficiency, reduce environmental impact, and improve the quality of the final product.

https://doi.org/10.15407/kataliz2024.35.032
Article PDF (Українська)

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