Physical-chemical properties of biodiesel fuels based on camelina oil ethyl esters
Article PDF (Українська)

Keywords

biodiesel fuel, fatty acids ethyl esters, camelina oil, rapeseed oil, physical-chemical properties, exploitation properties

How to Cite

Yakovlieva, A., Boichenko, S., Hudz, A., & Zubenko, S. (2020). Physical-chemical properties of biodiesel fuels based on camelina oil ethyl esters. Catalysis and Petrochemistry, (29), 24-31. https://doi.org/10.15407/kataliz2020.29.027

Abstract

This paper is devoted to the analysis of physical-chemical and exploitation properties of biodiesel fuels based on fatty acids ethyl esters of camelina oil and blended biodiesel fuels with different content of ethyl esters. The comparative analysis of samples of biodiesel fuels based on fatty acids methyl and ethyl esters of rapeseed and camelina oil was performed. It is shown that the fatty acids methyl and ethyl esters of rapeseed and camelina oils have physical-chemical properties, which significantly differ from those of traditional diesel fuels of petroleum origin. This is explained by the different chemical structure of ester molecules and molecules of fuel’s hydrocarbons. In this case, the fatty acids ethyl esters of camelina oil have properties, which are the most similar to the properties of conventional diesel fuel among studied esters. It is noted that fatty acids ethyl esters of camelina oil have high performance properties, in particular, lubricating ability, which will have positive effect on exploitation of diesel engines. The advantages and benefits of using camelina oil over rapeseed as an alternative feedstock for biodiesel production are formulated and outlined. The basic physical-chemical and ex-ploitation properties of mixed biodiesel fuels samples containing fatty acids ethyl esters of camelina oil in a quantity of 10%, 30% and 50% were fulfilled and comparative analysis with traditional diesel fuel of petroleum origin was carried out. It is shown that the properties of the studied samples of biodiesel fuel blends fully meet the requirements of the standards for both biodiesel fuel and traditional petroleum-based diesel fuel. This study substantiates the use of camelina oil for production of biodiesel, namely for the complete or partial replacement of traditional petroleum-based diesel fuel.

https://doi.org/10.15407/kataliz2020.29.027
Article PDF (Українська)

References

Kolodko T.H. Potentsial vyrobnytstva biopalyva v Ukraini: URL:http://www.btsau.kiev.ua/files/list/edition/ed_fkbijdakvh.pdf (document viewing: 19.02.2019 р). [In Ukrainian].
Shevchenko I.A., Poliakova O.I., Vedmedieva K.V., Komarova I.B. Ryzhii, saflor, kunzhut. Stratehiia vyrobnytstva oliinoi syrovyny v Ukraini (maloposhyreni kultury). Instytut oliinykh kultur Natsionalnoi akademii ahrarnykh nauk Ukrainy. Status. 2017. Р.40. [In Ukrainian].
Iakovlieva A.V., Boichenko S.V., Vovk O. O. Overview of innovative technologies for aviation fuels production. Chemistry and Chemical Technology. 2013, Vol. 7, № 3, P. 305-312. [In English]. https://doi.org/10.23939/chcht07.03.305
Iakovlieva A., Boichenko S., Lejda K., Vovk O., Shkilniuk I. Vacuum Distillation of Rapeseed Oil Esters for Production of Jet Fuel Bio-Additives, Procedia Engineering, 2017, Vol. 187, P. 363-370. DOI: [In English]. https://doi.org/10.1016/j.proeng.2017.04.387
Kryshtopa, S. Kryshtopa, L., Melnyk, V., Dolishnii, B., Prunko, I., Demianchuk, Y. (2017). Experimental research on diesel engine working on a mixture of diesel fuel and fusel oils. Transport problems, Vol. 12. No. 2, р. 53-63. [In English]. https://doi.org/10.20858/tp.2017.12.2.6
Demydas H., Kvitko H., Hetman N. Ryzhii posivnyi - oliina kul-tura alternatyvna ripaku yaromu dlia vyrobnytstva biodyzeliu. Zbirnyk naukovykh prats VNAU, 2011, № 8 (48). P. 3-8. [In Ukrainian].
Solis J.L., Berkemar A.L., Alejo, Kiros L. Biodiesel from rapeseed oil (Brassica napus) by supported Li2O and MgO. International Journal of Energy and Environmental Engineering. 2016. No.8,1. P.9-23. [In English]. https://doi.org/10.1007/s40095-016-0226-0
EN 14214:2003 «Automotive fuels - Fatty acid methyl esters (FAME) for diesel engines - Requirements and test methods» URL: http://en.wikipedia.org/wiki/EN_14214": (document viewing: 01.05.2019 р). [In English].
DSTU 6081:2009 Toplivo motornoe. Efiry metylovye zhyrnykh kyslot masel i zhirov dlia dizelnykh dvihatelei. Tekhnicheskye trebo-vanyia. [Chynnyi vid 01.03.2010]. Vyd.ofits. Kyiv: Derzh-spozhyvstandart Ukrainy, 2009. [In Ukrainian].
Panchuk M., Kryshtopa S., Shlapak L., Kryshtopa L., Yarovyi V., Sladkovskyi, A. Main trend of biofuels Production in Ukraine. Transport Problems. 2017. Vol. 12, No. 4. P. 95-103. [In English]. https://doi.org/10.20858/tp.2017.12.4.2
Issariyakul, T., Dalai, A. K. Biodiesel Production from Greenseed Canola Oil. Energy Fuels, 24, 9, 4652-4658, (2010). (document viewing: 18.12.2019). [In English]. https://doi.org/10.1021/ef901202b
Demirbas, A., Karslioglu, S. Biodiesel Production Facilities from Vegetable Oils and Animal Fats. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 29:2, 133-141, (2007). URL: (document viewing : 07.11.2019). [In English]. https://doi.org/10.1080/009083190951320
Moser B.R. Camelina (Camelina sativa L.) oil as a biofuels feedstock: Golden opportunity of false hope? Lipid technology. 2010. Vol. 22, № 12. P. 270 - 273. [In English]. https://doi.org/10.1002/lite.201000068
Zubenko S.O., Patryliak L.K., Konovalov S.V. Porivniannia fizyko-khimichnykh ta ekspluatatsiinykh vlastyvostei biodyzelnoho palyva na osnovi metanolu ta tiospyrtiv. Katalyz y neftekhymyia. 2018. № 27. P. 1 - 18. [In Ukrainian].
Patent 85034 Ukraina. MPK C 07 C 51/42, C 07 C 69/00, C 10 L 1/00, C 10 L 1/02. Patryliak L.K., Patryliak K.I., Okhrimenko M.V. Sposib oderzhannia etylovykh esteriv zhyrnykh kyslot. Ukraina.10.12.08. Biul. № 23. [In Ukrainian].
Cherian G. Camelina sativa in poultry diets: opportunities and challenges / Biofuel co-products as livestock feed. Opportunities and challenges, at Ed. Harinder P.S.M., 2012. Ch.17. P. 303 - 310. [In English].